A reexamination of the reactions of Ga (CH2SiMe3) 3 and In (CH2SiMe3) 3 with alkali-metal hydrides. The search for a reductive-elimination reaction
RB Hallock, OT Beachley Jr, YJ Li…
Index: Hallock, R. B.; Beachley, O. T. Jr.; Li, Yong-Ji; Sanders, William Michael; Churchill, Melvyn Rowen; et al. Inorganic Chemistry, 1983 , vol. 22, p. 3683 - 3691
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Citation Number: 34
Abstract
The nature of the reactions that occur between Ga (CH2SiMeS), and In (CH, SiMe,), with alkali-metal hydrides has been reinvestigated. The previously reported result^^^^ suggesting reductive elimination reactions have not been reproduced. The product from the reaction between Ga (CH2SiMe3) 3 and KH in benzene at 45 OC has been identified as KGa (CH2SiMe3) 3H by an X-ray structural study, infrared and'H NMR spectral data, and ...
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