New copper (I) and silver (I) triazolato-complexes: Synthesis, reactivity and catalytic activity in olefin cyclopropanation
GA Ardizzoia, S Brenna, F Castelli, S Galli…
Index: Ardizzoia, G. Attilio; Brenna, Stefano; Castelli, Fulvio; Galli, Simona; Marelli, Chiara; Maspero, Angelo Journal of Organometallic Chemistry, 2008 , vol. 693, # 10 p. 1870 - 1876
Full Text: HTML
Citation Number: 12
Abstract
A new class of azolate ligands, deriving from the equimolar condensation of 3, 5-diamino-1, 2, 4-triazole with salicylaldehyde (H3L1) and o-anisaldehyde (H3L2) was prepared. In their anionic form, these species act as bridging moieties upon coordination to Cu (I) and Ag (I), giving rise to the formation of dinuclear complexes with the ligand in the typical N, N′- exobidentate conformation. The copper derivative [Cu (H2L1)(CH3CN)] 2 (1) showed ...
Related Articles:
[Charette; Beauchemin; Francoeur Journal of the American Chemical Society, 2001 , vol. 123, # 33 p. 8139 - 8140]
A novel class of tunable zinc reagents (RXZnCH2Y) for efficient cyclopropanation of olefins
[Lorenz, Jon C.; Long, Jiang; Yang, Zhiqiang; Xue, Song; Xie, Yinong; Shi, Yian Journal of Organic Chemistry, 2004 , vol. 69, # 2 p. 327 - 334]
Silver-catalyzed reductive dehalogenation of 1, 1-dibromocyclopropanes
[Shimizu, Nobujiro; Watanabe, Kenji; Tsuno, Yuho Chemistry Letters, 1983 , p. 1877 - 1878]
Use of high pressure in the reduction of organic chlorides with tri-n-butyltin hydride
[Rahm, A.; Amardeil, R.; Degueil-Castaing, M. Journal of Organometallic Chemistry, 1989 , vol. 371, p. C4 - C8]
Silver-catalyzed reductive dehalogenation of 1, 1-dibromocyclopropanes
[Shimizu, Nobujiro; Watanabe, Kenji; Tsuno, Yuho Chemistry Letters, 1983 , p. 1877 - 1878]