The mechanism of the heterogeneous catalytic monooxidation of thiophene derivatives at the S position by hydrogen peroxide
IT Nagieva
Index: Nagieva Russian Journal of Physical Chemistry A, 2009 , vol. 83, # 11 p. 1873 - 1878
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Abstract
Abstract A biomimetic catalytic reaction system for hetero-oriented monooxidation of heteroaromatic compounds was developed experimentally. The system consisted of two interacting synchronous reactions of the decomposition of H 2 O 2 and substrate oxidation. The problem related to the preparation, isolation, and identification of thiophene derivative S- monoxides was solved.
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[Thiemann, Thies; Ohira, Daisuke; Arima, Kazuya; Sawada, Tsuyoshi; Mataka, Shuntaro; Marken, Frank; Compton, Richard G.; Bull, Steven D.; Davies, Stephen G. Journal of Physical Organic Chemistry, 2000 , vol. 13, # 10 p. 648 - 653]