Earth-Abundant Alkali Iron Phosphates (AFePO4) as Efficient Electrocatalysts for the Oxygen Reduction Reaction in Alkaline Solution

Chinnasamy Murugesan, Shubham Lochab, Baskar Senthilkumar, Prabeer Barpanda

Index: 10.1002/cctc.201701423

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Abstract

Abstract Water-splitting systems are essential for clean energy production. The oxygen reduction reaction (ORR) is a key reaction involved in water splitting, which requires a catalyst. The current work explores the possible application of sodium and potassium iron phosphates (AFePO4, A=Na and K) as electrocatalysts for ORR activity. These earth-abundant iron phosphates were synthesized by the solution combustion synthesis (SCS) technique by using ascorbic acid both as fuel and reducing agent for Fe. The crystal structure was analyzed by Rietveld refinement. The formation of carbon coating was identified by thermogravimetric analysis and Raman spectroscopy. Electrocatalytic properties of AFePO4 were investigated in alkali electrolytes for the first time by using linear sweep voltammetry with a rotating disk electrode (RDE). The ORR activities of these alkali iron phosphates are comparable to that of the Pt/C system. The Tafel slope and electron transfer number of the alkali iron phosphates were calculated. The ORR activity of NaFePO4 was found to be better than KFePO4 and FePO4. This work demonstrates alkali iron phosphates as alternate cost-effective, novel electrocatalysts for productive ORR activity in alkaline solution. Earth-abundant alkali FePO4: The maricite orthorhombic crystal structure is involved in the effective oxygen reduction reaction (ORR) catalytic process by utilizing a four-electron transfer reaction along with stabilization of active centers by the phosphate framework.