Aminolysis reaction of glycerol carbonate in organic and hydroorganic medium

…, L Candy, JF Blanco, Y Raoul, Z Mouloungui

Index: Nohra, Bassam; Candy, Laure; Blanco, Jean-Francois; Raoul, Yann; Mouloungui, Zephirin JAOCS, Journal of the American Oil Chemists' Society, 2012 , vol. 89, # 6 p. 1125 - 1133

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Citation Number: 15

Abstract

Abstract Aminolysis reaction of glycerol carbonate with primary amine in organic and hydroorganic media leads to the formation of two hydroxyurethane isomers and a partial decomposition of glycerol carbonate into glycerol. Aminolysis with a secondary amine promotes the condensation reaction and limits the formation of glycerol. The ratio of α versus β was determined by zgig 13 C NMR. This technique permits computing the yield of α and ...