Features of the reaction of polyfluoroalkyl chlorolsulfites with allyl alcohol

AI Rakhimov, AV Miroshnichenko

Index: Rakhimov; Miroshnichenko; Thao, Do Duong Phuong Russian Journal of General Chemistry, 2011 , vol. 81, # 8 p. 1640 - 1642

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Abstract

Abstract Unlike the saturated aliphatic and aromatic alcohols, allyl alcohol under the same conditions reacts with polyfluoroalkyl chlorosulfites to form not ethers, but polyfluorinated alcohols. The exception is polyfluoroalkyl chlorosulfites with the chain length of more than five carbon atoms. Allyl ethers of polyfluorinated alcohols of general formula CH 2= CHCH 2 OCH 2 (CF 2 CF 2) n H (n= 1–3) were obtained, when the reaction proceeded in the ...