Fluorinated C-Nitroso Compounds. II. 1 The Reaction of Nitric Oxide with Some Fluoroolefins in the Presence of Ferric Chloride

JD Park, AP Stefani, JR Lacher

Index: Park,J.D. et al. Journal of Organic Chemistry, 1961 , vol. 26, p. 3319 - 3323

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Citation Number: 7

Abstract

The fluorinated olefins tetrafluoroethylcne, trifluorochloroethylene and l, l-difluoro-2, 2- dichloroethylene react with nitric oxide in the presence of anhydrous ferric chloride to give good yields of the nitrosoethanes C1CF2CF, K0, C1CF2CFClN0, and CICF2CC12N0, respectively. Along with these compounds, which constitute the major part of the reaction mixture, are formed nitro-nitroso, nitro, and fully halogenated derivatives all of which have ...