Epoxidation with dioxiranes derived from 2-fluoro-2-substituted-1-tetralones and-1-indanones
DS Brown, BA Marples, P Smith, L Walton
Index: Brown, David S.; Marples, Brian A.; Smith, Paul; Walton, Lesley Tetrahedron, 1995 , vol. 51, # 12 p. 3587 - 3606
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Citation Number: 109
Abstract
Homochiral 2-fluoro-2-substituted-1-tetralones (10a, 10b, 13) and ethyl 2-fluoro-1-indanone- 2-carboxylate (16) have been isolated. The dioxirane derivatives of these ketones have been prepared in situ, and have been shown to epoxidise alkenes but not enantioselectively. The dioxirane derivative of methyl 2, 5, 7-trifluoro-1-indanone-2- carboxylate (18) has been shown to be comparatively efficient in epoxidation.
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