Organoboron compounds. Allylboration of carbonyl compounds with allyl (alkyl) boranes

BM Mikhailov, YN Bubnov, MS Grigoryan

Index: Mikhailov,B.M. et al. Journal of Organometallic Chemistry, 1978 , vol. 154, p. 131 - 145

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Citation Number: 22

Abstract

Abstract A convenient procedure for the synthesis of homoallylic alcohols from carbonyl compounds and allylboranes is described. Allyl-, 2-methylallyl-, crotyl-and 3, 3-dimethylallyl (dialkyl) boranes, as well as diallyl (alkyl) boranes and derivatives of 3-allyl-and 3-metallyl-3- borabicyclo [3.3. 1] non-6-ene are effective reagents for allylation of carbonyl compounds (aldehydes, ketones, esters, carboxylic acids and others) offering, in a number of cases, ...