Synthesis

A new strategy for the synthesis of furan-3, 4-dicarboxylic acid

AM Deshpande, AA Natu, NP Argade

Index: Deshpande, Anil M.; Natu, Arvind A.; Argade, Narshinha P. Synthesis, 2002 , # 8 p. 1010 - 1012

Full Text: HTML

Citation Number: 14

Abstract

Abstract A facile route to furan-3, 4-dicarboxylic acid is described. Dimethylmaleic anhydride (1) on NBS-bromination followed by aqueous KOH treatment gave bis (hydroxymethyl) maleic anhydride (3), which on intramolecular Mitsunobu ring closure followed by esterification and DDQ-oxidation furnished the desired esters of furan-3, 4-dicarboxylic acid 7a/b.

Related Articles:

Novel Preparation of 1-and 3-Substituted Bicyclo [3.2. 2] nona-3, 6, 8-trien-2-ones from Tropones and 2, 3-Bis (methoxycarbonyl)-7-oxabicyclo [2.2. 1] heptadiene by …

[Tian; Sugiyama; Mori; Takeshita Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 7 p. 2393 - 2399]

Triflic acid-mediated rearrangements of 3-methoxy-8-oxabicyclo [3.2. 1] octa-3, 6-dien-2-ones: synthesis of methoxytropolones and furans

[Williams, Yvonne D.; Meck, Christine; Mohd, Noushad; Murelli, Ryan P. Journal of Organic Chemistry, 2013 , vol. 78, # 23 p. 11707 - 11713]

Synthesis and reactions of β-substituted derivatives of furan

[Jurasek, Adolf; Zvak, Vladimir; Kovac, Jaroslav; Rajniakova, Olga; Stetinova, Jarmila Collection of Czechoslovak Chemical Communications, 1985 , vol. 50, # 9 p. 2077 - 2083]

Thermoneutral dyotropic transfer of hydrogen in a hydrocarbon

[Hagenbuch, Jean-Pierre; Stampfli, Brigitte; Vogel, Pierre Journal of the American Chemical Society, 1981 , vol. 103, # 13 p. 3934 - 3935]

Novel Preparation of 1-and 3-Substituted Bicyclo [3.2. 2] nona-3, 6, 8-trien-2-ones from Tropones and 2, 3-Bis (methoxycarbonyl)-7-oxabicyclo [2.2. 1] heptadiene by …

[Tian; Sugiyama; Mori; Takeshita Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 7 p. 2393 - 2399]

More Articles...