An Efficient Catalytic Oxidation of p-Alkoxypenols to p-Quinones Using Tetrabutylammonium Bromide and Oxone
T Yakura, A Ozono, K Morimoto
Index: Yakura, Takayuki; Ozono, Ayaka; Morimoto, Kohei Chemical and Pharmaceutical Bulletin, 2011 , vol. 59, # 1 p. 132 - 134
Full Text: HTML
Citation Number: 10
Abstract
A catalytic oxidation of p-alkoxyphenols was developed using tetrabutylammonium bromide (TBAB) and Oxone®. The reaction of p-alkoxyphenol (1) with a catalytic amount of TBAB in the presence of Oxone® as a co-oxidant in acetonitrile–water (2: 1) gave the corresponding p-quinone (2) in excellent yield without special treatment.
Related Articles:
[Zalomaeva, Olga V.; Sorokin, Alexander B. New Journal of Chemistry, 2006 , vol. 30, # 12 p. 1768 - 1773]
Radikalische Alkylierung von Chinonen: Erzeugung von Radikalen in Redoxreaktionen
[Jacobsen,N.; Torrsell,K. Justus Liebigs Annalen der Chemie, 1972 , vol. 763, p. 135 - 147]
[Ley, Steven V.; Thomas, Andrew W.; Finch, Harry Journal of the Chemical Society - Perkin Transactions 1, 1999 , # 6 p. 669 - 671]
Radikalische Alkylierung von Chinonen: Erzeugung von Radikalen in Redoxreaktionen
[Jacobsen,N.; Torrsell,K. Justus Liebigs Annalen der Chemie, 1972 , vol. 763, p. 135 - 147]
[Cao, Sheng; Christiansen, Robin; Peng, Xiaohua Chemistry - A European Journal, 2013 , vol. 19, # 27 p. 9050 - 9058]