The (Porphyrin) ruthenium??Catalyzed Aziridination of Olefins Using Aryl Azides as Nitrogen Sources

…, A Caselli, C Piangiolino, F Ragaini…

Index: Fantauzzi, Simone; Gallo, Emma; Caselli, Alessandro; Piangiolino, Cristiana; Ragaini, Fabio; Cenini, Sergio European Journal of Organic Chemistry, 2007 , # 36 p. 6053 - 6059

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Citation Number: 26

Abstract

Abstract Aryl azides have been used as atom-efficient nitrene transfer reagents in the (porphyrin) ruthenium-catalyzed amination of olefins. Several azides, olefins and [Ru (porphyrin) CO] complexes were tested to investigate the scope and limits of the reaction. Quantitative yields and short reaction times were achieved by using terminal olefins and aryl azides bearing electron-withdrawing groups on the aryl moiety. The reactions were ...

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