Synthesis of Polymers Containing Lipoic Acid Structure and Study of the Acyl Transfer Reaction
M Okawara, A Fujimoto, T Endo
Index: Okawara,M. et al. Israel Journal of Chemistry, 1978 , vol. 17, p. 264 - 268
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Citation Number: 6
Abstract
Abstract Several S-acetyl and S, S-diacetyl derivatives of dihydrolipoic acid and amide were prepared as model compounds to examine acyl transfer reactions similar to those in living systems. A macromolecule bearing the lipoic acid (1, 2-dithiolane) structure was synthesized by polymer reaction of polyacrylamide. The acyl transfer from these S-acetates to nucleophiles such as amine, alcohol and thiol as well as the catalytic behavior of silver ion ...
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