Reaction of enol silyl ethers with silver acetate-iodine. Synthesis of. alpha.-iodo carbonyl compounds
GM Rubottom, RC Mott
Index: Rubottom,G.M.; Mott,R.C. Journal of Organic Chemistry, 1979 , vol. 44, p. 1731 - 1734
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Citation Number: 47
Abstract
Method B (In Situ Method). In these experiments the catalyst was generated in situ from [(nor- CiHs) RhCl]~ z and the ditertiary phosphine (C~ HR)* PCH (C~ H~) CH? P (C~ H~)~ using a phosphorus/rhodium mole ratio of 2 2 1 and a substrate/catalyst ratio of 100: l. The hydrogenations were conducted at TO bars of hydrogen pressure in 20-mL stainless steel autoclaves at room temperature overnight. A catalyst for a typical in situ experiment was ...
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