Cobalt (I)-catalyzed stereoselective olefination of alkylzinc reagents with aldehydes
JX Wang, Y Fu, Y Hu, K Wang
Index: Wang, Jin-Xian; Fu, Ying; Hu, Yulai; Wang, Kehu Synthesis, 2003 , # 10 p. 1506 - 1510
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Citation Number: 15
Abstract
The reaction of alkylzinc reagents and carbonyl compounds represents one of the most reliable methods to prepare optically active secondary alcohols. [7] [8] In addition, we have also reported that the substitution reaction of nitro group [9] and dialkylation reaction [10] of alkylzinc reagents using [Ni(acac) 2 ] as a catalyst in the presence of a tertiary amine and silylating agent. Recently, we have reported the stereoselective synthese of (E)-stilbenes [11] by the ...
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