Silver–Sulfur Hybrid Supertetrahedral Clusters: The Hitherto Missing Members in the Metal–Chalcogenide Tetrahedral Clusters

Geng-Geng Luo, Hai-Feng Su, An Xiao, Zhi Wang, Yang Zhao, Qiao-Yu Wu, Ji-Huai Wu, Di Sun, Lan-Sun Zheng

Index: 10.1002/chem.201703468

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Abstract

Rise of the silver sulfur: Two silver–sulfur supertetrahedral clusters (SCs) with modified geometry were synthesized through ligand control and characterized by single-crystal X-ray diffraction. Their physical properties were also investigated. These are the first representatives of structurally determined silver–sulfur T3 superclusters so far.