Borylation of organo halides and triflates using tetrakis (dimethylamino) diboron
CS Bello, J Schmidt-Leithoff
Index: Bello, Charles S.; Schmidt-Leithoff, Joachim Tetrahedron Letters, 2012 , vol. 53, # 46 p. 6230 - 6235,6
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Citation Number: 5
Abstract
We report a new in situ borylation method using tetrakis (dimethylamino) diboron, DMA4B2, in the presence of a diol. Our method uses standard borylation conditions and readily available Pd-catalysts. The scope of this method includes aryl halides and triflates as well as vinyl halides and triflates. The method successfully works with a broad range of diols, enabling the selection of the best boronic ester for subsequent Suzuki coupling.
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