Doped complex bases, a new consequence of aggregative activation

B Jamart-Grégoire, Y Fort, MJ Quirin…

Index: Jamart-Gregoire, Brigitte; Fort, Yves; Quirin, Marie-Jeanne; Caubere, Paul Journal of the Chemical Society, Chemical Communications, 1992 , # 19 p. 1459 - 1460

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Citation Number: 3

Abstract

Sodium amide containing complex bases (CB) NaNH2-RONa are useful reagents to generate carbanions and trigger anionic polymerisations as well as to perform syn eliminations or elimination-additions. 1 According to the basic principles of aggregative activation2 CB properties may be easily modified by changing the nature of the activating agent RONa. These possibilities have been largely exploited. l.2 Aggregative acti- vation also leads to the expectation that ...