Phosphoramidate solvolysis
I Oney, M Caplow
Index: Oeney,I.; Caplow,M. Journal of the American Chemical Society, 1967 , vol. 89, p. 6972 - 6980
Full Text: HTML
Citation Number: 25
Abstract
Abstract: The solvolytic properties of mono-and dimethyl esters of phosphoramidic acid are reported and compared with previously published data on unsubstituted phosphoramidate. The similarity of the rate constants for the hydrolysis (0.58 hr-l) and solvolysis in 50 2 vjv methanol-water (0.296 hr-I) of neutral monomethyl phosphoramidate at 36.8” to those for neutral phosphoramidic acid suggest a common (bimolecular) mechanism for both ...
Related Articles:
[Leslie, D. Ralph; Beaudry, William T.; Szafraniec, Linda L.; Rohrbaugh, Dennis K. Journal of Organic Chemistry, 1991 , vol. 56, # 10 p. 3459 - 3462]
[Leslie, D. Ralph; Beaudry, William T.; Szafraniec, Linda L.; Rohrbaugh, Dennis K. Journal of Organic Chemistry, 1991 , vol. 56, # 10 p. 3459 - 3462]
Solvolysis of diphenyl amidophosphates in aqueous alcoholic media
[Kasparek, Frantisek; Mollin, Jiri Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 2 p. 386 - 396]