Synthesis, properties, and molecular structure of nitro-substituted N-methyl-N-nitroanilines

…, AS Bykova, OV Prezhdo, Z Daszkiewicz…

Index: Prezhdo; Bykova; Daszkiewicz; Kyziol; Zaleski Russian Journal of General Chemistry, 2006 , vol. 76, # 1 p. 64 - 75

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Abstract

Abstract Ten mono-, di-, and trinitro derivatives of N-methyl-N-nitroaniline were synthesized and studied by spectral, electrooptical, and quantum-chemical methods. Three of these derivatives, N-methyl-N, 2, 3-trinitroaniline, N-methyl-N, 2, 5-trinitroaniline, N-methyl-N, 3, 5- trinitroaniline, were also examined by the X-ray diffraction method. The N-nitroamino group in their molecules is almost planar, the N 7-N 8 bond is shortened, and the N 8 atom is ...