A useful method for selective acylation of alcohols using 2, 2'-bipyridyl-6-yl carboxylate and cesium fluoride.
T Mukaiyama, FC Pai, M Onaka, K Narasaka
Index: Mukaiyama, Teruaki; Pai, Fong-Chang; Onaka, Makoto; Narasaka, Koichi Chemistry Letters, 1980 , p. 563 - 566
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Citation Number: 26
Abstract
Primary and secondary alcohols are acylated under mild conditions by the use of 2, 2′- bipyridyl-6-yl carboxylates and cesium fluoride. Furthermore, the reaction is successfully applied to selective acylation of a primary carbinol group of diols containing primary and secondary carbinol groups or exclusive O-acylation of aromatic amino alcohols.
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