Lewis??Acid??Catalyzed Benzylic Reactions of 2??Methylazaarenes with Aldehydes
…, G Hong, S Wu, X Liu, J Yu, L Wang
Index: Mao, Dan; Hong, Gang; Wu, Shengying; Liu, Xin; Yu, Jianjun; Wang, Limin European Journal of Organic Chemistry, 2014 , vol. 2014, # 14 p. 3009 - 3019
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Citation Number: 8
Abstract
Abstract Lewis-acid-catalyzed benzylic reactions of 2-methylazaarenes with aldehydes have been investigated. Series of azaarene derivatives were afforded by this reaction. 2-(Pyridin- 2-yl) ethanols with common substituents were formed through the LiNTf 2-promoted aldol reaction for the first time. 2-Alkenylpyridines, exclusively in the form of the E isomers, were synthesized in the presence of LiNTf 2 cooperated with H 2 NTf. In the presence of La (Pfb ...
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