Nature of the electronic interactions in aryl-substituted polysilanes

CG Pitt, RN Carey, EC Toren Jr

Index: Pitt,C.G. et al. Journal of the American Chemical Society, 1972 , vol. 94, p. 3806 - 3811

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Citation Number: 115

Abstract

Abstract: The ionization potentials and half-wave reduction potentials of a series of a- naphthyl-and phenyl-substituted polysilanes have been determined and used to elucidate the nature of the electronic interactions between aryl and polysilanyl groups. It is shown that the relative energies of the u and a electrons have a substantial in-fluence on the energy and character of the highest occupied molecular orbital, and hence the electronic spectra ...