The Journal of Organic Chemistry

Amine-hydroperoxide adducts. Use in synthesis of silyl alkyl peroxides

YL Fan, RG Shaw

Index: Fan,Y.L.; Shaw,R.G. Journal of Organic Chemistry, 1973 , vol. 38, p. 2410 - 2412

Full Text: HTML

Citation Number: 20

Abstract

Synthesis by the Amine-Hydroperoxide Adduct Method.-The amine-hydroperoxide adduct synthesis of silyl peroxides requires two steps:(1) preparation of the amine-hydroperoxide adduct;(2) reaction of the adduct with chlorosilane in an inert solvent. Preparation of the adduct is carried out by mixing stoichiometric amounts of a suitable amine and the hydroperoxide in an inert solvent. 6 Assuming that the proper sol-vent has been selected, ...