Organoboron Compounds. XX. Chemistry of Some 1-Naphthaleneboronic Acids with Substituents in the 8-Position1

RL Letsinger, JM Smith, J Gilpin…

Index: Letsinger,R.L. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 807 - 812

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Citation Number: 8

Abstract

ole.^ Thus, boron trichloride was passed into a melt of 2-(l-naphthyl) benzimidazole at 310- 320'in the absence of an added catalyst. Following hydrolysis, two materials were obtained. One, soluble in ethanol, dimethylformamide, acetic acid, aqueous hydrochloric acid, and aqueous alkali, proved to be the desired 2-(8-borono-1-naphthyl) benzimidazole. It was isolated in 24% yield. The other, insoluble in alcohol and in 10% aqueous sodium ...