Gas-phase reactions of charged electrophiles with styrene and phenylacetylene

ME Crestoni, S Fornarini

Index: Crestoni, Maria Elisa; Fornarini, Simonetta Journal of the American Chemical Society, 1989 , vol. 111, # 16 p. 6008 - 6014

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Citation Number: 7

Abstract

Conclusion The present work points to the possibility of deriving the activation parameters for the thermal, unimolecular isomerization of a gaseous cation from a systematic temperature-dependence study, carried out with the now well-established radiolytic technique in different gases in a wide pressure range, and utilizing different reactions for the preparation of the ion of interest. The usefulness of such an approach can be desumed ...