Synthetic communications

A novel reductive cyclization of arylmethylidenemalononitrile promoted by low-valent titanium

D Shi, H Zhao, X Wang, C Yao, L Zhou

Index: Shi, Daqing; Zhao, Hong; Wang, Xiangshan; Yao, Changsheng; Zhou, Longhu Synthetic Communications, 2002 , vol. 32, # 21 p. 3311 - 3317

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Abstract

Low-valent titanium reagents have an exceedingly high ability to promote the reductive coupling of carbonyl compounds and are attracting increasing interest in organic synthesis. A lot of other functional groups can also be coupled.1-2 View all references Although several results have been reported on saturated carbonyl compounds, only a few studies on the coupling α,β-unsaturated cabonyl compounds have been published.3-4 View all references Recently, we have ...

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