Chlorination of aliphatic ketones in methanol
RR Gallucci, R Going
Index: Gallucci, R. R.; Going, R. Journal of Organic Chemistry, 1981 , vol. 46, # 12 p. 2532 - 2538
Full Text: HTML
Citation Number: 21
Abstract
Results Methanol solutions of acetone, 2-butanone, 3-methyl-2-butanone, or 4-heptanone were allowed to react with 1 or 2 equiv of chlorine at 20-50" C. Chlorine is bubbled into the reaction mixture. After a short induction period, the yellow solution becomes colorless and the temperature increases. When addition of 1 equiv of chlorine is complete, the solution turns yellow and cooling of the reaction is necessary. The reaction products at this point ...
Related Articles:
[Jagdale, Arun R.; Chouthaiwale, Pandurang V.; Sudalai, Arumugam Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2009 , vol. 48, # 10 p. 1424 - 1430]
[Abraham, Raymond J.; Tormena, Claudio F.; Rittner, Roberto Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 8 p. 1663 - 1667]