Détermination de structures au moyen de la RMNn du 29 Si: Transfert sélectif de population avec les méthylchlorodisilylméthanes

…, J Dunogues, B Barbe, M Petraud, M Lefort

Index: Deleris, G.; Birot, M.; Dunogues, J.; Barbe, B.; Petraud, M.; Lefort, M. Journal of Organometallic Chemistry, 1984 , vol. 266, # 1 p. 1 - 8

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Citation Number: 13

Abstract

Abstract The selective population transfer (SPT) technique has been applied to 29 Si NMR of the complete series of methylchlorodisilylmethanes, several of which are new compounds. A great enhancement of the signals was observed and unambiguous assignments based on the determination of 2 J (Si H) coupling constants could be made. The first example of this type is presented.