The Photolysis of Diazomethyl t-Butyl Ketone
KB Wiberg, TW Hutton
Index: Wiberg; Hutton Journal of the American Chemical Society, 1954 , vol. 76, p. 5367,5370
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Citation Number: 30
Abstract
The photolysis of diazoketones with ultraviolet light has been investigated in order to determine whether this might be a convenient alternate method for effecting the WOE rearrangement.'The advantages of such a method would be that steric hindrance should not affect this reaction and that diazoketones derived from optically active secondary acids might not be racemized under these conditions. 2 The ketene which is presumed to be an ...
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