Journal of organometallic chemistry

A novel and convenient preparation of hypophosphite esters

S Deprèle, JL Montchamp

Index: Deprele, Sylvine; Montchamp, Jean-Luc Journal of Organometalic Chemistry, 2002 , vol. 643-644, p. 154 - 163

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Citation Number: 35

Abstract

Only a few methods have been described for the preparation of hypophosphite esters (alkyl phosphinates, ROP (O) H2). As a result, comparatively few applications have been reported, and these intermediates have not been widely exploited in organophosphorus chemistry despite their synthetic potential. Herein, we describe a very general, practical, and high- yielding synthesis of hypophosphite esters, based on the reaction of hypophosphorous ...

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