Indolequinone Antitumor Agents: Correlation between Quinone Structure, Rate of Metabolism by Recombinant Human NAD (P) H: Quinone Oxidoreductase, and in …

…, N O'Sullivan, SJ Green, R Bien, D Siegel…

Index: Beall, Howard D.; Winski, Shannon; Swann, Elizabeth; Hudnott, Anna R.; Cotterill, Ann S.; O'Sullivan, Noeleen; Green, Stephen J.; Bien, Richard; Siegel, David; Ross, David; Moody, Christopher J. Journal of Medicinal Chemistry, 1998 , vol. 41, # 24 p. 4755 - 4766

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Citation Number: 95

Abstract

A series of indolequinones bearing various functional groups has been synthesized, and the effects of substituents on the metabolism of the quinones by recombinant human NAD (P) H: quinone oxidoreductase (NQO1) were studied. Thus 5-methoxyindolequinones were prepared by the Nenitzescu reaction, followed by functional group interconversions. The methoxy group was subsequently displaced by amine nucleophiles to give a series of ...

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