ACS Catalysis

Mild Hydrosulfenylation of Olefins under Neutral Conditions Using a Defined NHC-Ligated Iron–Sulfur Catalyst

I Alt, P Rohse, B Plietker

Index: Alt, Isabel; Rohse, Philipp; Plietker, Bernd ACS Catalysis, 2013 , vol. 3, # 12 p. 3002 - 3005

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Citation Number: 9

Abstract

A defined NHC-Fe–S complex proved to be an efficient catalyst for the selective hydrosulfenylation of α, β-unsaturated ketones or vinylnitriles. A wide range of different aliphatic thiols were transferred in this atom-economic reaction into the corresponding thioethers. Mild reaction conditions, equimolar amounts of substrates, low catalyst loadings, and mild reaction conditions are characteristic for this transformation.

Bifunctional acid–base ionic liquid for the one-pot synthesis of fine chemicals: Thioethers, 2H-chromenes and 2H-quinoline derivatives

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Thia-michael addition reactions using 2-[bis (alkylthio) methylene]-3-oxo-No-tolylbutanamides as odorless and efficient thiol equivalents

[Dong, Dewen; Yu, Haifeng; Ouyang, Yan; Liu, Qun; Bi, Xihe; Lu, Yumei Synlett, 2006 , # 2 p. 283 - 287]

A mild and highly efficient one-pot three-component reaction for carbon–sulfur bond formation catalyzed by potassium tert-butoxide

[Movassagh, Barahman; Rakhshani, Amir Chinese Chemical Letters, 2011 , vol. 22, # 10 p. 1179 - 1182]