Removal of sugar dithioacetal group with N-bromosuccinimide

…, D Dropkin, P Hagel, M Habash-Marino

Index: Miljkovic, Momcilo; Dropkin, Daniel; Hagel, Peter; Habash-Marino, Margaret Carbohydrate Research, 1984 , vol. 128, p. 11 - 20

Full Text: HTML

Citation Number: 12

Abstract

Abstract Oxidative removal of the dithioacetal group of several protected sugar and 2- acylamido-2-deoxy sugar dialkyl dithioacetals with N-bromosuccinimide in 97% aqueous acetone or 1: 1 (v/v) 2-methyl-2-propanol—acetone was compared with removal with mercury dichloride—mercury (II) oxide or mercury dichloride—cadmium carbonate. In general, removal with N-bromosuccinimide proceeded more rapidly, and, with one ...