Factors in the formation of isomerically and optically pure alkyl halides. Part V. Conditions which determine the formation of 2-halogeno-2-methyl-and 2-halogeno-3- …

HR Hudson

Index: Hudson,H.R. Journal of the Chemical Society [Section] B: Physical Organic, 1968 , p. 664 - 667

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Citation Number: 7

Abstract

Gas–liquid chromatography shows that the preparation of 1-halogeno-2, 2- dimethylpropanes from the corresponding alcohol may be accompanied by the formation of 2-halogeno-2-methylbutanes and 2-halogeno-3-methylbutanes. The latter are frequently observed in bromide or iodide systems and are thought to result from isomerization of the first formed t-halides. Rearrangements occurring during the reactions of 2, 2- ...