The infrared spectrum of aminodifluoroborane, NH2BF2: Partial assignment of the fundamentals and analysis of the band near 1608 cm-1

HM Jemson, W Lewis-Bevan…

Index: Jemson, H. M.; Lewis-Bevan, W.; Gerry, M. C. L. Canadian Journal of Chemistry, 1988 , vol. 66, p. 2088 - 2099

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Citation Number: 2

Abstract

The infrared spectrum of gas phase aminodifluoroborane, NH2BF2, has been observed for the first time. A partial assignment to the fundamental vibrations has been made. The band has been recorded at high resolution, and the rotational and centrifugal distortion constants of NH211F2 have been obtained in both the ground and 21 levels. A small rotational perturbation in the 21 level has been attributed to a perpendicular Coriolis interaction. ...