Tetrahedron

Synthesis of 1, 3-dioxin-4-ones having chiral hydroxyalkyl groups at the 6-position by means of baker's yeast reduction and their uses for epc synthesis

J Sakaki, Y Sugita, M Sato, C Kaneko

Index: Sakaki, Jun-Ichi; Sugita, Yoshiaki; Sato, Masayuki; Kaneko, Chikara Tetrahedron, 1991 , vol. 47, # 32 p. 6197 - 6214

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Citation Number: 21

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Prochiral methyl ketones connected with 6-(4-oxo-1,3-dioxinyl) group directly or through methylene chain (1–3) gave, by treatment with fermenting baker's yeast, the corresponding (S)-alcohols which served as synthons for a variety of enantiomerically pure compounds.