Single-flask preparation of polyazatriaryl ligands by sequential borylation/Suzuki–Miyaura coupling
B Avitia, E MacIntosh, S Muhia, E Kelson
Index: Avitia, Bertoldo; MacIntosh, Eric; Muhia, Samuel; Kelson, Eric Tetrahedron Letters, 2011 , vol. 52, # 14 p. 1631 - 1634
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Citation Number: 8
Abstract
We report a convenient single-flask methodology for the preparation of polyazatriaryl products with relevance to luminescence, catalysis, and pharmacology. The diborylation of 1, 3-dibromobenzenes and double Suzuki–Miyaura coupling produces 1, 3- diheteroarylbenzenes. Similarly, borylation of heteroaryl halides and double coupling to 2, 6- dichloropyridine produces 2, 6-diheteroarylpyridines. This methodology appears general ...
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