The Reactions of Certain Aldoximes with Diazomethane

AF Thompson Jr, M Baer

Index: Thompson; Baer Journal of the American Chemical Society, 1940 , vol. 62, p. 2095

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Citation Number: 2

Abstract

Summary Catalytic hydrogenation of mesitil by the method of Thompson has been made to yield either the cis-or trans-enediol. Similar pairs of isomers have been made by this method from 2, 6-xylil and 2, 2', 4, 4', 6, 6'-hexaethylbenzil. It has been shown in each instance that the cis form can be changed to the corresponding trans form by prolonged contact with hydrogen in the presence of platinum.

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