Methylenecyclohexenes: inversion barriers from the far-infrared spectra
TL Smithson, N Ibrahim…
Index: Smithson, Tracy L.; Ibrahim, Nan; Wieser, Hal Canadian Journal of Chemistry, 1983 , vol. 61, p. 442 - 453
Full Text: HTML
Citation Number: 9
Abstract
The far-infrared spectra of 3-methylenecyclohexene, 4-methylenecyclohexene, and 1-methyl- 3-methylenecyclohexene in the region of 80-400 cm-1 are reported and interpreted mainly with a view to the two lowest out-of-plane deformations of the cyclohexene ring. Typical C- type band sequences are observed and interpreted in terms of ring inversion modes. Barriers to inversion are determined by means of a one-dimensional Hamiltonian with a ...
Related Articles:
[Gassman, Paul G.; Bonser, Steven M. Tetrahedron Letters, 1983 , vol. 24, # 33 p. 3431 - 3434]
[Gassman, Paul G.; Bonser, Steven M.; Mlinaric-Majerski, Kata Journal of the American Chemical Society, 1989 , vol. 111, # 7 p. 2652 - 2662]
[Gassman, Paul G.; Bonser, Steven M. Tetrahedron Letters, 1983 , vol. 24, # 33 p. 3431 - 3434]
[Aitken, R. Alan; Hodgson, Philip K.G.; Morrison, John J.; Oyewale, Adebayo O. Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 3 p. 402 - 415]
Umsetzungen des Cyclohex??3??en??carbaldehyd??p??toluolsulfonylhydrazons
[Rey,M. et al. Helvetica Chimica Acta, 1968 , vol. 51, p. 1001 - 1010]