Tetrahedron letters

Studies on the effects of substituents on rate enhancements in intramolecular diels-alder reactions: Reasons for the gem-dimethyl effect

ME Jung, J Gervay

Index: Jung, Michael E.; Gervay, Jacquelyn Tetrahedron Letters, 1988 , vol. 29, # 20 p. 2429 - 2432

Full Text: HTML

Citation Number: 67

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Comparison of the rates of cyclization of a series of 2-furfuryl methyl fumarates leads to the conclusion that the gem-dimethyl effect is due primarily to higher population of reactive rotamers. ... Comparison of the rates of cyclization of a series of the 2-furfuryl methyl fumarates 3 (prepared from ...

Related Articles:

Stereospecific Construction of Chiral Tertiary and Quaternary Carbon by Nucleophilic Cyclopropanation with Bis (iodozincio) methane

[Nomura, Kenichi; Matsubara, Seijiro Chemistry - An Asian Journal, 2010 , vol. 5, # 1 p. 147 - 152]

gem-Dialkyl effect in the intramolecular Diels-Alder reaction of 2-furfuryl methyl fumarates: the reactive rotamer effect, the enthalpic basis for acceleration, and …

[Jung, Michael E.; Gervay, Jacquelyn Journal of the American Chemical Society, 1991 , vol. 113, # 1 p. 224 - 232]

More Articles...