Radical cyclization reactions of. alpha.-silyl amine. alpha.,. beta.-unsaturated ketone and ester systems promoted by single electron transfer photosensitization
YT Jeon, CP Lee, PS Mariano
Index: Jeon, Yoon T.; Lee, Chao-Pin; Mariano, Patrick S. Journal of the American Chemical Society, 1991 , vol. 113, # 23 p. 8847 - 8863
Full Text: HTML
Citation Number: 79
Abstract
Abstract: The results of a broad investigation of the preparative and mechanistic aspects of single electron transfer (SET) promoted photocyclization reactions of a-silyl amino and amido a,@-unsaturated esters and ketones are presented. A number of unique and synthetically useful features of these processes, driven by a-silyl amine and amide cation radical desilylation and by intramolecular conjugate addition of intermediate a-amino and ...
Related Articles:
Total Synthesis of Indolizidine (+)??223A
[Fellah, Mouloud; Lhommet, Gerard; Mouries-Mansuy, Virginie European Journal of Organic Chemistry, 2012 , # 3 p. 463 - 465]
Oxidative methods for promoting iminium cation cyclization reactions
[Zhang; Jung; Mariano; Fox; Martin; Merkert Tetrahedron Letters, 1993 , vol. 34, # 33 p. 5239 - 5242]
Total Synthesis of Indolizidine (+)??223A
[Fellah, Mouloud; Lhommet, Gerard; Mouries-Mansuy, Virginie European Journal of Organic Chemistry, 2012 , # 3 p. 463 - 465]
Total Synthesis of Indolizidine (+)??223A
[Fellah, Mouloud; Lhommet, Gerard; Mouries-Mansuy, Virginie European Journal of Organic Chemistry, 2012 , # 3 p. 463 - 465]