Allylboration of nitrosobenzene

YN Bubnov, DG Pershin, AL Karionova…

Index: Bubnov, Yurii N.; Pershin, Dmitrii G.; Karionova, Anna L.; Gurskii, Mikhail E. Mendeleev Communications, 2002 , vol. 12, # 5 p. 202 - 204

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Citation Number: 4

Abstract

The allylboration of nitrosobenzene at –70 °C resulted in the formation of N- and O-allyl derivatives of N-phenylhydrazine, which were reduced with the second allylborane molecule to N-allylaniline above 100 °C. ... The heating of nitrosoarenes with trialkylboranes afforded cor- responding anilines in low yields; the products of reductive alkylation were not detected.1–3 The reactions of nitroaromatic substrates with allylboranes occurred at 80–100 °C and resulted in ...

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