Preparation and palladium-catalysed arylation of indolylzinc halides

…, Y Kondo, N Takazawa, H Yamanaka

Index: Sakamoto, Takao; Kondo, Yoshinori; Takazawa, Nobuo; Yamanaka, Hiroshi Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 16 p. 1927 - 1934

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Citation Number: 35

Abstract

Faculty of Pharmaceutical Sciences, Tohoku University Aobayama, Aoba-ku, Sendai 980- 77, Japan ... Indolylzinc halides are prepared by two methods: transmetallation of indolyllithiums with zinc chloride and oxidative addition of active zinc to iodoindoles. The palladium-catalysed reaction of the indolylzinc halides provides a practical method for synthesizing arylindoles. ... Organozinc derivatives have importance in synthetic organic chemistry because of their ...