Synthesis, thermal stability, and chemiluminescence properties of the dioxetanes derived from 1, 4-dioxins
W Adam, EM Peters, K Peters, H Platsch…
Index: Adam, Waldemar; Peters, Eva-Maria; Peters, Karl; Platsch, Herbert; Schmidt, Ernst; et al. Journal of Organic Chemistry, 1984 , vol. 49, # 21 p. 3920 - 3928
Full Text: HTML
Citation Number: 12
Abstract
Photoeensitized singlet oxygenation of benze and naphtho-1, 4-dioxins 3 afforded the Corresponding 1, 2-dioxetanes 4 in moderate to good yields. Ene products 7 were obtained in those cases in which the 1, 4-dioxins 3 bear alkyl substituents. Thermal decomposition of the 1, 2-dioxetanes 4 afford the corresponding diesters 5 essentially quantitatively. The X- ray crystal structures of the dioxetanes 4g, 4h, and 4j indicate that the four-membered ...
Related Articles:
[Ishihara, Kazuaki; Kubota, Manabu; Kurihara, Hideki; Yamamoto, Hisashi Journal of Organic Chemistry, 1996 , vol. 61, # 14 p. 4560 - 4567]
Does diatomic sulfur (S2) react as a free species?
[Steliou, Kosta; Salama, Paul; Yu, Xiaoping Journal of the American Chemical Society, 1992 , vol. 114, # 4 p. 1456 - 1462]
[Marette, Caroline; Larrouquet, Camille; Tisnes, Pierre; Deloye, Jean-Bernard; Gras, Emmanuel Tetrahedron Letters, 2006 , vol. 47, # 39 p. 6947 - 6950]