Tetrahedron

… Endoperoxidte Analogs Via Benzylpalladation of Bicyclic Alkenes. 22For a preliminary communication see: Larock, RC; Babu, S. Tetrahedron Lett. 1985, 26, 2763.

RC Larock, S Babu

Index: Larock, Richard C.; Babu, Srinivasan Tetrahedron, 1987 , vol. 43, # 9 p. 2013 - 2020

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Citation Number: 18

Abstract

The reactions of norbornene, norbornadiene and 7-oxanorbornene with methyl 3- (chloromethyl) phenoxyacetate (4), optically pure (S)-1-octyn-3-ol (5), and 8% Pd (PPh3) 4 afford in one step satisfactory yields of the corresponding esters 6, 7 and 8 respectively, readily saponified to the first interphenylene prostaglandin endoperoxide analogs 10, 11 and 12 respectively.