Metallacycle transfer from zirconium to main group elements: A versatile synthesis of heterocycles

…, WA Nugent, JC Calabrese

Index: Fagan, Paul J.; Nugent, William A.; Calabrese, Joseph C. Journal of the American Chemical Society, 1994 , vol. 116, # 5 p. 1880 - 1889

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Citation Number: 293

Abstract

Abstract: The reaction of zirconium metallacycles is used to produce a variety of main group heterocycles including borole Diels-Alder dimers, galloles, indacyclopentadienes, siloles, germoles, stannoles, phospholes, arsoles, stiboles, bismoles, thiophenes, selenophenes, dihydrothiophenes, dihydroselenophenes, tetrahydrothiophenes, tetrahydroselenophenes, stannacyclopentanes, phospholenes, and isothiazoles. An X-ray crytallographic study of ...