Vinyl-substituted Polysilanes

H Sakurai, K Tominaga, M Kumada

Index: Sakurai,H. et al. Bulletin of the Chemical Society of Japan, 1966 , vol. 39, # 6 p. 1279 - 1282

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Citation Number: 26

Abstract

1-Vinylheptamethyltrisilane, 2-vinylheptamethyltrisilane and vinylpentamethyldisilane have been prepared from the corresponding chlorosilanes and vinylmagnesium chloride. In these compounds, intense absorption maxima were observed in the ultraviolet region, and both the λ max and ε increased with an increase in the chain length. Nuclear magnetic resonance and infrared data are also recorded here. Free radical copolymerizations were carried out ...