On anchimerically assisted homolysis via sulphide functions

AJ Lawson

Index: Lawson, Alexander J. Journal of the Chemical Society, Chemical Communications, 1981 , # 23 p. 1238 - 1239

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Abstract

In contrast to O–O fission, anchimeric assistance from sulphide functions in the rate of unimolecular fission of the N–O bond is only marked for heterolysis reactions; analogous homolyses are very much less accelerated, although bridged radical intermediates are involved.