In (III)-mediated chemoselective dehydrogenative interaction of ClMe2SiH with carboxylic acids: Direct chemo-and regioselective Friedel-Crafts acylation of aromatic …
SA Babu, M Yasuda, A Baba
Index: Babu, Srinivasarao Arulananda; Yasuda, Makoto; Baba, Akio Organic Letters, 2007 , vol. 9, # 3 p. 405 - 408
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Citation Number: 32
Abstract
Chemoselective dehydrogenative interaction of ClMe2SiH with a carboxylic acid group in the presence of InX3 is reported. 13C NMR investigation revealed the formation of PhCOOSi (Cl) Me2 as the major transient intermediate. Chemo-and regioselective Friedel-Crafts acylation of aromatic ethers directly from carboxylic acids was established.
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